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"Physical Chemistry" by Peter Atkins and Julio de Paula is a renowned textbook that provides an in-depth introduction to the principles of physical chemistry. The book covers topics such as thermodynamics, quantum mechanics, spectroscopy, and statistical mechanics.
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If you absolutely cannot afford any version, consider that MIT’s 5.61 (Physical Chemistry) course uses McQuarrie and provides free lecture notes that parallel the book. While not a PDF of the text, these notes (available on MIT OCW) often contain the core derivations. "Physical Chemistry" by Peter Atkins and Julio de
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